Boosting Hydroformylation via Reactant Enrichment in Covalent Triazine Frameworks with Atomically Dispersed Rh.

Xinguo Li, Xiangjie Zhang, Gaolei Qin, Peng He, Yajuan Hao

Abstract read

In one paragraph

Article in Materials (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

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2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

5 authors.

Xinguo LiSchool of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China.

Xiangjie ZhangState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China.

Gaolei QinState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China.

Peng HeState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China.

Yajuan HaoSchool of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China.

Funding

the National Key R&D Program of China No.2023YFB4103102

6 · The paper itself

Abstract

Hydroformylation is one of the most widely applied homogeneous catalytic processes in the chemical industry, constituting the predominant manufacturing platform for aldehyde synthesis at commercial scales. Nevertheless, hydroformylation shares with traditional homogeneous catalysis the inherent limitation of difficult catalyst recovery and recycling. Developing heterogeneous catalysts for such reactions is thus critically needed. Herein, a stable nitrogen-rich covalent triazine framework (CTF) was synthesized via a mild Friedel-Crafts alkylation method and employed as a support for Rh single-atom catalysts (Rh/CTF-TPA). In the hydroformylation of 1-decene, the Rh/CTF-TPA catalyst exhibits an exceptional reaction efficiency (TOF > 1900 h

Indexed as

covalent triazine frameworksheterogeneous catalysthydroformylationlong chain olefin

Identifiers

PMID40572824

DOI10.3390/ma18122691

PMCPMC12193888

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.