ArticleNanomaterials (Basel, Switzerland)2025
Exciting High-Order Plasmon Mode Using Metal-Insulator-Metal Bowtie Nanoantenna.
Article in Nanomaterials (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Noble metal nanostructures have garnered significant attention for their exceptional optical properties, particularly Localized Surface Plasmon Resonance (LSPR), which enables pronounced near-field electromagnetic enhancements. Among these, bowtie nanoantennas (BNAs) are distinguished by their intense plasmonic coupling within nanogap regions, making them highly effective for applications such as surface-enhanced Raman scattering (SERS). However, the practical utility of conventional BNAs is often hindered by small hotspot areas and significant scattering losses at their peak near-field enhancement wavelengths. To overcome these limitations, we have designed a novel notch metal-insulator-metal bowtie nanoantenna (NMIM-BNA) structure. This innovative design integrates dielectric materials with Ag-BNA nanostructures and strategically positions arrays of silver (Ag) nanorods within the central nanogap. By coupling the larger NMIM-BNA framework with these smaller Ag nanorod arrays, higher-order plasmon modes (often referred to as dark modes) are effectively excited. Consequently, the NMIM-BNA exhibits substantial electric field enhancement, particularly at the Fano dip wavelength, arising from the efficient coupling of these higher-order plasmon modes with dipole plasmon modes. Compared to conventional Ag-BNA nanoantennas, our NMIM-BNA provides a significantly larger hotspot region and an enhanced near-field amplification factor, underscoring its strong potential for advanced SERS applications.
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