ArticleACS nanoscience Au2025
Unraveling Element-Selective Local Structures in Multielement Alloy Nanoparticles with EXAFS.
Article in ACS nanoscience Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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15 authors.
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Abstract
We demonstrate physically consistent and interpretable extended X-ray absorption fine structure (EXAFS) curve-fitting analyses for estimating element-selective local structures in multielement alloy nanoparticles (MEA NPs). The difficulty in analyzing multielement systems originates from the too large number of independent structural parameters to fit, far exceeding the information content of the typical experimental data. Herein, this challenge is overcome by simultaneously fitting multiple data at different absorption edges and temperatures while imposing constraints based on a physically reasonable model. Another advantage of our approach is interpretability; the individual contributions of the constituent elements to the static and dynamic structures are explicitly estimated as atomic radii and Einstein temperatures. This method is used to analyze MEA NPs composed of platinum-group metals and
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