ArticleChemical science2025
Crown ether-cycloparaphenylene hybrid multimacrocycles: insights into supramolecular gas sensing and biological potential.
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- The advent of molecular nanocarbon biology.Chemical science · 2026Review
- Synergistic HChemistry, an Asian journal · 2026Article
- Highly Selective Construction of DSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- A dual-responsive cationic acridinium nanohoop: redox activity and acid/base-controlled reversible guest capture and release.Chemical science · 2026Article
- Exploring the World of Double Nanohoops.Angewandte Chemie (International ed. in English) · 2026Review
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Authors and funding
12 authors.
Funding
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Abstract
The topologically intriguing multimacrocyclic architecture is endowed with distinct physical and chemical properties. The synthesis of hybrid macrocycles combining crown ethers and cycloparaphenylenes (CPPs) presents a promising strategy for developing multifunctional supramolecular systems. Herein, we first report the precise construction of a series of crown ether-CPP hybrid multimacrocycles with enhanced photophysical properties and diverse host-guest interactions. Notably, the trimacrocyclic hybrid adopts a molecular tweezer-like conformation, resulting in a significantly higher fullerene binding affinity compared to the bismacrocycle. The fullerene complex showed improved conductivity and sensitivity with a limit of detection (LOD) of 19 ppb for NO
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