ArticleACS nano2025
Finite Volume Effects in Water Nanodroplets: A Molecular Level Investigation.
Article in ACS nano, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
2 citing papers in PubMed.
- Spiers Memorial Lecture: Vibrations at interfaces.Faraday discussions · 2026Article
- Comment on "Can Charge Transfer Across C─H···O Hydrogen Bonds Stabilize Oil Droplets in Water?"Angewandte Chemie (International ed. in English) · 2026Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Aqueous interfaces are responsible for a plethora of processes. At the nanoscale, interfaces are overwhelmingly influenced by finite volume effects that are thought to impact both molecular level and macroscopic properties. Here, finite volume effects are investigated using electrophoretic mobility and vibrational sum frequency scattering of water nanodroplets in oil and oil nanodroplets in water, made from the same chemicals. Notably, there is a substantial difference in the orientational ordering of water between the two aqueous interfaces. Isotope dilution studies reveal that water outside the oil droplets participates significantly in intramolecular coupling, while water inside the droplets predominantly exhibits intermolecular coupling. These spectral variations underlie different water structures, pointing to a larger heterogeneity inside water droplets, which are explained by finite volume effects that include a pronounced difference in electrostatics.
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