ArticleAngewandte Chemie (International ed. in English)2025
A Phenomenological Symmetry Rule for Chemical Reactivity Under Vibrational Strong Coupling.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Ultrafast triggering of strong coupling in a semiconductor terahertz Fabry-Pérot cavity.Light, science & applications · 2026Article
- A macroscopic condensation theory for vibrational strong coupling effects.Nature communications · 2026Article
- Toward Reliable Spectroscopic Analysis of Reaction Kinetics in Polaritonic Chemistry.Nanophotonics (Berlin, Germany) · 2026Article
- Validating free spectral range tracking as a robust method for mitigating artifacts in VSC kinetics.RSC advances · 2026Article
- Collective Rabi-Driven Vibrational Activation in Molecular Polaritons.Nano letters · 2026Article
- Collectively-Modified Intermolecular Electron Correlations: The Connection of Polaritonic Chemistry and Spin Glass Physics.Chemical reviews · 2026Review
- Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Density-functional tight binding meets Maxwell: unraveling the mysteries of (strong) light-matter coupling efficiently.Nanophotonics (Berlin, Germany) · 2025Article
- Cavity Field-Driven Symmetry Breaking and Modulation of Vibrational Properties: Insights from the Analytical QED-HF Hessian.Journal of chemical theory and computation · 2025Article
- A Phenomenological Symmetry Rule for Chemical Reactivity Under Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2025Article
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9 authors.
Funding
Abstract
Symmetry is known to strongly influence the course of a chemical reaction. It has also been found to play a key role in vibrational strong coupling (VSC), where it can influence the outcome of chemical reactions or alter chemical equilibria. However, the precise nature of this effect and its extent remains elusive. To further explore the role of vibrational symmetry, we have investigated the equilibrium constants of different charge transfer complexes, in particular of isomers of trimethyl benzene belonging to different point groups from which a general symmetry rule emerges. We describe the strongly coupled system by a direct product of irreducible representations associated with the complexes and the cavity. As a consequence, the coupled vibration is associated with a new irreducible representation that projects differently on the reaction coordinate of the charge transfer complexation, reflecting the changes in the equilibrium constants. This phenomenological symmetry rule points to a general underlying framework for predicting the outcome of chemical reactivity under VSC.
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