Evidence map›Paper›PMID 40540364›Full record

ArticleThe Journal of organic chemistry2025

The Mechanism of the Rappe Rearrangement─A Stereochemical Investigation Using Density Functional Theory.

Toby J Sommer, Henry S Rzepa

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Toby J SommerIndependent Researcher, P.O. Box 541092, Waltham, Massachusetts 02454, United States.ORCID 0009-0005-9496-7785
Henry S RzepaDepartment of Chemistry, Imperial College, Molecular Sciences Research Hub, White City Campus, 82 Wood Lane, London W12 0BZ, England.ORCID 0000-0002-8635-8390

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Since it was first described in the 1950s, there has been no explanation of the extraordinarily high selectivity for the formation of the thermodynamically less stable

Identifiers

PMID40540364
PMCPMC12235638

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.