ArticleJournal of chemical theory and computation2025
Combining Optical Control and Geometrical Optimization for Efficient Control of Competing Molecular Photoinduced Processes Far from the Ground State.
Article in Journal of chemical theory and computation, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
1 citing paper in PubMed.
- Preparing Superposition States to Modify the Spectra and to Achieve Complete Selectivity in Photodissociation Reactions.Journal of chemical theory and computation · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The yield of a photochemical process can be maximized by optimizing the driving fields, such as in optical control, or the initial wave function, as in geometrical optimization. We combine both algorithms in an iterative process, showing very fast convergence and great improvement in the yields, as applied to driving population to the second excited state of the molecular hydrogen cation through the first excited dissociative state by a pump-pump scheme. The results reveal the impact of the initial vibrational coherences in photoinduced processes that occur at nuclear configurations very far from the ground state, or that are even mediated by processes in the continuum. On the other hand, depending on whether we maximize the total electronic population (that mainly dissociates) or the bound population, the initial wave functions change considerably, involving nodal patterns in the position or in the momentum representations, respectively, that lead to different dynamics.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.