Evidence map›Paper›PMID 40534495›Full record

ArticleJournal of the American Chemical Society2025

Asymmetric C-H Amination via Fe(III)-Metalloradical Catalysis Featuring α-Fe(IV)-Aminyl Radicals as Key Intermediates.

Wan-Chen Cindy Lee, Duo-Sheng Wang, Arghya Deb, Yiling Zhu, X Peter Zhang

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Iron-Catalyzed Cyclopropanation of Allenes Using Unactivated Alkyl Sulfonium Salts.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Article
  3. Article
  4. Review
  5. Enantioselective radical chemistry: a bright future ahead.Beilstein journal of organic chemistry · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Wan-Chen Cindy LeeDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0002-2433-7404
Duo-Sheng WangDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0002-3519-2386
Arghya DebDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0001-7607-3941
Yiling ZhuDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0002-9827-9673
X Peter ZhangDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0001-7574-8409

Funding

Catalytic Processes for Stereoselective Radical Cyclization ReactionsR01GM102554 · NIGMS · BOSTON COLLEGE · PI ZHANG, X. PETER · 2015 to 2024
$3.4M
Stereoselective Radical Processes for C-H Alkylation and AminationR01GM132471 · NIGMS · BOSTON COLLEGE · PI ZHANG, X. PETER · 2020 to 2023
$1.7M
CryoProbe-enabled Bruker AVANCE NEO 500 MHz NMR SpectrometerS10OD026910 · OD · BOSTON COLLEGE · PI JAYASUNDERA, THUSITHA · 2021 to 2021
$1000k
Bruker D8 VENTURE DiffractometerS10OD030360 · OD · BOSTON COLLEGE · PI LI, BO · 2022 to 2022
$428k
NIGMS NIH HHS R01 GM102554NIGMS NIH HHS R01 GM132471NIH HHS S10 OD026910NIH HHS S10 OD030360
6 · The paper itself

Abstract

Metalloradical catalysis (MRC) offers a general mechanistic platform for controlling the reactivity and selectivity of homolytic radical reactions. While Co(II)-based d

Identifiers

PMID40534495
PMCPMC12269175

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.