Evidence map›Paper›PMID 40531817›Full record

ArticlePloS one2025

Exploring the hydrophobic effects of quaternary ammonium copolymers on corrosion of casing and tubing steel in acidic solution.

Ghadeer Mubarak, Chandrabhan Verma, Mohammad A Jafar Mazumder, Imad Barsoum, Akram Alfantazi

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Article in PloS one, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

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2citing papers in PubMed
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1 · What the graph read from it

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

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4 · The record

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Ghadeer MubarakDepartment of Petroleum and Chemical Engineering, Khalifa University of Science and Technology, Abu Dhabi, United Arab Emirates.
Chandrabhan VermaDepartment of Petroleum and Chemical Engineering, Khalifa University of Science and Technology, Abu Dhabi, United Arab Emirates.ORCID 0000-0001-9249-7242
Mohammad A Jafar MazumderDepartment of Chemistry, King Fahd University of Petroleum & Minerals, Dhahran, Saudia Arabia.
Imad BarsoumDepartment of Mechanical Engineering, Khalifa University of Science and Technology, Abu Dhabi, United Arab Emirates.
Akram AlfantaziDepartment of Petroleum and Chemical Engineering, Khalifa University of Science and Technology, Abu Dhabi, United Arab Emirates.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

By encouraging improved adsorption onto metal surfaces and creating a more powerful barrier against corrosive chemicals, the hydrophobic property of corrosion inhibitors raises inhibition efficiency and decreases corrosion rates. This work aims to synthesize and describe three quaternary ammonium-based copolymers (AMCs) with different hydrophobic qualities and investigate their ability to inhibit P110 CS corrosion in 15% HCl, which is helpful for casing and tubing. The results showed that AMCs act as efficient corrosion inhibitors, with over 90% inhibition efficiency ([Formula: see text] ) at 20 ppm concentration. The electrochemical investigation results indicated that the AMCs with hydrophilic and hydrophobic ratios of 100 (5), 90:10 (6a), and 80:20 (6b) manifest [Formula: see text] of 87.74%, 92.12%, and 93.53%, respectively. The electrochemical investigations show that at the metallic surface's active areas, AMCs successfully replace the pre-adsorbed water molecules. They are categorized as mixed-type corrosion inhibitors because they prevent both anodic and cathodic reactions without appreciably changing the corrosion potential ([Formula: see text]). Their adsorption on the metallic surface follows the Langmuir adsorption isotherm. Surface analysis tools like SEM and EDX are utilized to investigate the corrosion prevention mechanism of adsorption. The DFT analysis results show that quaternary nitrogen atoms of hydrophilic and hydrophobic moieties play a key role in the adsorption and charge-sharing processes. Finally, the corrosion prevention mechanism of AMCs is explained using a graphic depiction based on the ideas of electrochemical, surface, and computational studies.

Indexed as

PolymersQuaternary Ammonium CompoundsSteelAdsorptionCorrosionHydrophobic and Hydrophilic InteractionsSolutionsSurface PropertiesPolymersQuaternary Ammonium CompoundsSolutionsSteel

Identifiers

PMID40531817
PMCPMC12176120

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.