ArticleAngewandte Chemie (International ed. in English)2025
Zwitterionic Heavier Pnictinidenes in Redox Catalysis.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Speciation-Controlled C-F Bond Functionalization Enabled by Zwitterionic Pnictinidenes.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth-Ligand Cooperation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Smallest acyclic tricationic molecule containing a Bis(phosphine)-stabilized low-valent triantimony-based Unit.Nature communications · 2026Article
- A Crystalline In(II) Hydride.Journal of the American Chemical Society · 2026Article
- Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C-H/O Activation, and 6-electron Redox Transmetalation in Planar Bismuth Triamides.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis of PChemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Flash Communication: Bismuthinidenes as Lewis Bases in Reversible C(spOrganometallics · 2025Article
- Zwitterionic Heavier Pnictinidenes in Redox Catalysis.Angewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Herein, we describe a new class of zwitterionic heavier pnictogen species with bis(N-heterocyclic carbene)borate as ligands, enabling the isolation of stable Sb and Bi species in multiple oxidation states. Computational analysis of zwitterionic pnictinidenes revealed their cationic character at the metal centre while holding unique electronic properties that contribute to their nucleophilicity and stability. These systems participate in oxidative addition and reductive elimination processes, and display redox catalytic activity in hydrodefluorination reactions, marking a unique example of cationic pnictinidene catalysing a redox transformation and providing reactivity beyond the constraints of pincer ligands. Additionally, we report on a novel dehydrogenative thiolation of silanes. This work expands the scope of low-valent pnictogen chemistry, providing a novel platform for main group redox catalysis.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.