Evidence map›Paper›PMID 40526830›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Interplay Between Stereochemically Active Lone Pair Repulsions, Sigma Hole Interactions, and Delocalized Redox Processes in Topochemical Fluoride-Ion Insertion.

Anindya Pakhira, Shruti Hariyani, George Agbeworvi, Jaime R Ayala, Conan Weiland, Cherno Jaye, Daniel A Fischer, Lu Ma, Sarbajit Banerjee

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Anindya Pakhira *Department of Chemistry, Texas A&M University, College Station, TX, 77843, USA.ORCID https://orcid.org/0009-0005-3326-8382
Shruti Hariyani *Department of Chemistry, Texas A&M University, College Station, TX, 77843, USA.ORCID https://orcid.org/0000-0002-4707-8863
George AgbeworviDepartment of Chemistry, Texas A&M University, College Station, TX, 77843, USA.ORCID https://orcid.org/0000-0002-2126-1854
Jaime R AyalaDepartment of Chemistry, Texas A&M University, College Station, TX, 77843, USA.ORCID https://orcid.org/0000-0003-2730-4525
Conan WeilandMaterial Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD, 20899, USA.ORCID https://orcid.org/0000-0001-6808-1941
Cherno JayeMaterial Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD, 20899, USA.ORCID https://orcid.org/0000-0001-6158-6373
Daniel A FischerMaterial Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD, 20899, USA.
Lu MaNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, 11973, USA.ORCID https://orcid.org/0000-0001-9646-0738
Sarbajit BanerjeeDepartment of Chemistry, Texas A&M University, College Station, TX, 77843, USA.ORCID https://orcid.org/0000-0002-2028-4675

Funding

Welch Foundation A-1978-20190330
6 · The paper itself

Abstract

Topochemical insertion/extraction of cations has emerged as a generalizable strategy for modulating the crystal and electronic structure of periodic solids. In contrast, strategies for topochemical anion insertion are poorly explored and fundamental principles for designing insertion hosts to accommodate anions remain scarce. Here, we observe reversible room-temperature fluoride-ion insertion within tunnels of Sn

Indexed as

Anion insertionDative interactionsEnergy storageFluoride‐ion batteriesSigma‐hole interactionsUnconventional redox

Identifiers

PMID40526830
PMCPMC12338408

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.