ArticleInorganic chemistry2025
Mechanism of Gold-Catalyzed Arylation-Lactonization: A Density Functional Theory Study on the Role of the (MIC^N)AuCl Complex in Au(I)/Au(III) Catalysis.
Article in Inorganic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Synergistic Action of Ascorbic Acid and Readily Accessible NHC^N Ligands for the Oxidation of Gold(I) With Electron-Rich Aryldiazonium Salts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
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4 authors.
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Abstract
Gold-catalyzed redox transformations via Au(I)/Au(III) cycles offer efficient oxidative addition and reductive elimination under mild, oxidant-free conditions. Recent studies highlight the role of hemilabile mesoionic carbene (MIC) ligands in stabilizing key intermediates. Using DFT, we investigated the mechanism of the arylation-lactonization of γ-alkenoic acids, revealing two viable pathways,
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