ArticleThe journal of physical chemistry. B2025
The Importance of Hydrogen Bonded Networks in the Dynamic Heterogeneity of Deep Eutectic Solvents.
Article in The journal of physical chemistry. B, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Competitive Hydrogen-Bond Partitioning in Deep Eutectic Solvents: From Cooperative Charge Spreading to Structure-Property Design Rules.ACS omega · 2026Article
- Photophysical Properties of Coumarin 343 and Structural Changes in Reline-Pluronic Systems With Varying Block Composition.Chemistry, an Asian journal · 2026Article
- The Direct Piezoelectric Effect in Deep Eutectic Solvents.Journal of the American Chemical Society · 2026Article
- Do Dipolar Cosolvents Mitigate Microheterogeneity in Deep Eutectic Solvents? Solvation Dynamics and Solute Rotations in Glyceline/Methanol Solutions.The journal of physical chemistry. B · 2026Article
- Designing Ternary Chiral DES to Enhance Enantioselectivity.ACS omega · 2025Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We have examined the composition-dependent rotational diffusion dynamics of the chromophores perylene (neutral), oxazine 725 (cationic) and disodium fluorescein (anionic) in a series of choline chloride/1,3-propanediol (ChCl/PD) deep eutectic solvents (DESs). We find that the rotational diffusion dynamics of all chromophores do not correlate with the bulk viscosities of any of these ChCl/PD DES compositions, consistent with dynamic heterogeneity in all cases. Comparison with other DES systems─choline chloride/ethylene glycol (ChCl/EG) and choline chloride/glycerol (ChCl/Gly)─enables evaluation of the influence of hydrogen bond donor (HBD) structure and hydroxyl group density. This comparison highlights the critical role of hydrogen-bonded networks in these DESs and underscores the pivotal function of ChCl in disrupting these networks at ca. 15 mol % ChCl across all three DES systems. Taken collectively, these data point to the constituent structural factors that mediate the properties of DESs on local and bulk scales.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.