ArticleACS polymers Au2025
RAFT with Light: A User Guide to Using Thiocarbonylthio Compounds in Photopolymerizations.
Article in ACS polymers Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
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- Bypassing Heteronuclear MRI: Metal-Free Organosilicon Nanotracers for Background-Free HotspotAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Article
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- Reversible, Polymeric Complexation of Therapeutic Peptides Using Esterification.ACS macro letters · 2026Article
- Dual-Pathway Strategy for Click-Type Functionalization and Programmable Polymer Deconstruction.Macromolecules · 2026Article
- Copolymers of NVAm and NVP for Efficient Gene Delivery.ACS polymers Au · 2026Article
- Leveraging molecular descriptors and explainable machine learning for monomer conversion prediction in photoinduced electron transfer-reversible addition-fragmentation chain transfer polymerization.Scientific reports · 2026Article
- RAFT Step-Growth Polymerization via 'Grafting Through'.ACS polymers Au · 2025Article
- Oxygen-Tolerant, Red Light-Driven Controlled Synthesis of Easily Degradable and High Molecular Weight α-Lipoic Acid-Vinyl Copolymers.Angewandte Chemie (International ed. in English) · 2025Article
- Universal Bulk-Fill Composites: An Investigation into the Efficiency of Rapid Curing with Reversible Addition-Fragmentation-Chain Transfer (RAFT)-Mediated Polymerisation.Materials (Basel, Switzerland) · 2025Article
- Red Light-Driven, Oxygen-Tolerant RAFT Polymerization Enabled by Methylene Blue.Journal of the American Chemical Society · 2025Article
- Leveraging reactivity to gain precise control over macromolecular structures with photocatalysis in reversible-deactivation radical polymerizations.Chemical science · 2025Review
- Reversing Blocking Order of Trithiocarbonate-Mediated RAFT Polymerizations Using Photocatalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Solvent and temperature effects in the photoiniferter RAFT polymerisation of PEG methacrylate.Polymer chemistry · 2025Article
- PVAylation: precision end-functionalized poly(vinyl alcohol) for site-selective bioconjugation.Chemical science · 2025Article
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7 authors.
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No grant is acknowledged in the PubMed record.
Abstract
This perspective offers an in-depth guide to photopolymerizations mediated with thiocarbonylthio compounds, with a particular focus on photoiniferter and photoinduced energy/electron transfer RAFT (PET-RAFT) polymerizations, focusing on practical considerations. It is designed to provide both newcomers and experts with the practical knowledge needed to harness light-mediated polymerizations for innovative applications. The discussion begins with an overview of conventional RAFT polymerization and proceeds to highlight the distinctive advantages of the photomediated processes. The photochemical behavior of thiocarbonylthio compounds, along with the selection of appropriate light wavelengths, is critically examined for its impact on polymerization kinetics and optimization of polymer properties. Key parameters influencing polymerization successsuch as catalyst selection, solvent choice, light intensity, and temperatureare explored in detail. The importance of oxygen tolerance and end-group fidelity is also addressed, as these factors are essential for achieving well-defined polymers. Additionally, reactor configurations are reviewed, focusing on the roles of light sources, reactor geometry (batch versus flow systems), and temperature control in optimizing the reaction efficiency. The article concludes by integrating these concepts into a comprehensive framework for optimizing photoiniferter and PET-RAFT polymerizations.
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