Effect of Waterglass on the Hydration Process of Slag-Fly Ash-Based Geopolymer.

Geopolymers possess good mechanical properties and durability, and their partial replacement of traditional Portland cement is noteworthy for promoting the development of low-carbon building materials. To clarify the influence mechanism of the mechanical properties of slag-fly ash-based geopolymer mortar, this paper investigated the hydration heat, composition, and morphology of hydration products with various contents and moduli of waterglass. The results showed that the compressive strength of geopolymer mortar increased with increasing waterglass content, and first rose and then fell as the waterglass modulus raised, while its flexural strength increased and then decreased with the growth in both. The compressive and flexural strength of geopolymer mortar with 1.2-modulus waterglass at 20 wt% cured for 28 days were 88.4 MPa and 9.0 MPa, respectively. The hydration temperature and cumulative hydration heat of geopolymer mortar was elevated with the increase in waterglass content, and declined with the rising waterglass modulus. The hydration products of the geopolymer consisted of dense amorphous and flocculent structures wrapped around each other. The microstructure of the geopolymer cured for 3 days was loose when the content of 1.4-modulus waterglass was 5 wt%. The relative areas of the flocculation in the geopolymer cured for 28 days increased while the waterglass modulus was greater than 1.4, forming an interface with the dense amorphous structure generated during the early hydration stage, leading to a decrease in its mechanical properties. Therefore, it is recommended for slag-fly ash geopolymer mortar that the waterglass modulus is between 1.2 and 1.4 and its content is no less than 10 wt% to ensure suitable mechanical properties. This study also provided a referenceable time period for the pouring and operation of the engineering application of slag-fly ash-based geopolymer repair mortar.