Evidence map›Paper›PMID 40507870›Full record

ArticleInternational journal of molecular sciences2025

Phosphazenyl Phosphine Proton Sponges: Does the Proton-Chelating Effect Enhance Their Basicity?

Zoran Glasovac, Danijela Barić, Ines Despotović, Borislav Kovačević

Abstract read
In one paragraph

Article in International journal of molecular sciences, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Zoran GlasovacDivision of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia.
Danijela BarićDivision of Physical Chemistry, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia.
Ines DespotovićDivision of Physical Chemistry, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia.
Borislav KovačevićDivision of Physical Chemistry, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia.ORCID 0000-0002-8000-4508

Funding

Croatian Science Foundation IP-2024-05-7730
6 · The paper itself

Abstract

Gas-phase basicity and basicity in acetonitrile solvent were investigated for a series of proton sponges derived from phosphazenyl phosphines. A range of aromatic and aliphatic scaffolds bearing phosphazenyl phosphine substituents were employed to modulate the basicity of these compounds, primarily by varying the distance between the phosphazenyl phosphine units. These proton sponges were shown to be exceptionally strong organic bases, with p

Indexed as

Chelating AgentsPhosphinesProtonsAcetonitrilesHydrogen BondingAcetonitrilesChelating AgentsphosphinePhosphinesProtonsbasicityphosphazenyl phosphinespKaproton spongesquantum chemical calculations

Identifiers

PMID40507870
PMCPMC12155318

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.