Evidence map›Paper›PMID 40498980›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Atypical Hydrogen Bond Interaction Enables Anion-Rich Solvation Structure in Polymer Electrolytes for High-Voltage Flexible Lithium Metal Batteries.

Shujing Wen, Junhua Zhou, Guangzhao Zhang, Qingrong Wang, Chao Luo, Ruo Wang, Pengxian Li, Chaoyang Wang, Xiaoxiong Xu, Yonghong Deng and 2 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Shujing WenDepartment of Applied Biology and Chemical Technology, Faculty of Science, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, SAR, 999077, China.
Junhua ZhouDepartment of Applied Biology and Chemical Technology, Faculty of Science, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, SAR, 999077, China.
Guangzhao ZhangDepartment of Materials Science and Engineering, School of Innovation and Entrepreneurship, Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong, Southern University of Science and Technology, Shenzhen, 518055, China.
Qingrong WangDepartment of Materials Science and Engineering, School of Innovation and Entrepreneurship, Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong, Southern University of Science and Technology, Shenzhen, 518055, China.
Chao LuoDepartment of Materials Science and Engineering, School of Innovation and Entrepreneurship, Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong, Southern University of Science and Technology, Shenzhen, 518055, China.
Ruo WangDepartment of Materials Science and Engineering, School of Innovation and Entrepreneurship, Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong, Southern University of Science and Technology, Shenzhen, 518055, China.
Pengxian LiDongguan Key Laboratory of Interdisciplinary Science for Advanced Materials and Large-Scale Scientific Facilities, School of Physical Sciences, Great Bay University, Dongguan, Guangdong, 523000, China.
Chaoyang WangResearch Institute of Materials Science, South China University of Technology, Guangzhou, 510640, China.
Xiaoxiong XuDepartment of Materials Science and Engineering, School of Innovation and Entrepreneurship, Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong, Southern University of Science and Technology, Shenzhen, 518055, China.
Yonghong DengDepartment of Materials Science and Engineering, School of Innovation and Entrepreneurship, Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong, Southern University of Science and Technology, Shenzhen, 518055, China.
Jian ChangDepartment of Materials Science and Engineering, School of Innovation and Entrepreneurship, Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong, Southern University of Science and Technology, Shenzhen, 518055, China.
Zijian ZhengDepartment of Applied Biology and Chemical Technology, Faculty of Science, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, SAR, 999077, China.ORCID https://orcid.org/0000-0002-6653-7594

Funding

Guangdong Basic and Applied Basic Research Foundation 2022A1515011005Guangdong Provincial Key Laboratory of Energy Materials for Electric Power 2018B030322001High level of special funds G03050K002Hong Kong Polytechnic University U-CDBSHong Kong Polytechnic University U-ZEZ0National Natural Science Foundation of China 22109066National Natural Science Foundation of China 22371116NSFC/RGC Collaborative Research Scheme CRS_PolyU504/22Research Impact Fund of Hong Kong R5019-22Shenzhen Science and Technology Program JCYJ20220818100218040Shenzhen Science and Technology Program (JCYJ20220818100407016
6 · The paper itself

Abstract

Flexible lithium metal batteries (LMBs) using polymer-based solid-state electrolytes (PSSEs) are highly desirable for wearable applications because of the potential advantages in energy density and safety. Recently, ether-based polyelectrolytes have received extensive attention because of their good stability, high ionic conductivity, and Li metal anode compatibility. However, it typically forms organic-rich cathode electrolyte interphase (CEI) at the cathode, which is still a pain point that impedes the high-voltage performance. To address this challenge, herein a fluorinated plasticizer, bis(2-fluoroethyl) ether (BFE) is reported, which can be easily blended into ether-based PSSE and enables high-voltage-stable flexible LMBs. The BFE and PSSE molecules form an atypical hydrogen bond interaction, which weakens the interaction between PSSE and lithium ions. This leads to the formation of an anion-rich solvation structure that generates inorganic-rich and high-voltage-stable CEI. The oxidation stability of PSSE is improved from 4.4 V to over 4.7 V after introducing the BFE molecules. LMBs using BFE-blended PSSE can couple with high-voltage cathode and retain 80% capacity after 480 cycles at 1C. Full cells show high energy density (752.2 Wh L

Indexed as

atypical hydrogen bondhigh‐voltage lithium metal batteryinterphasepolymer solid electrolytesolvation structure

Identifiers

PMID40498980
PMCPMC12442591

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.