Evidence map›Paper›PMID 40492823›Full record

ArticleJournal of the American Chemical Society2025

Iridium Polypyridyl Carboxylates as Excited-State PCET Catalysts for the Functionalization of Unactivated C-H Bonds.

Diego A Granados, Y Emily Du, Shiloh J Andersson, Avery Cirincione-Lynch, Kai Cui, Adam Reinhold, Philip D Jeffrey, Gregory D Scholes, Sharon Hammes-Schiffer, Robert R Knowles

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Diego A GranadosDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.
Y Emily DuDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0003-0634-910X
Shiloh J AnderssonDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.
Avery Cirincione-LynchDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.ORCID 0009-0009-0310-0166
Kai CuiDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0001-7311-1447
Adam ReinholdDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.
Philip D JeffreyDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0002-4351-5341
Gregory D ScholesDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0003-3336-7960
Sharon Hammes-SchifferDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0002-3782-6995
Robert R KnowlesDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0003-1044-4900

Funding

New Synthetic Methods Enabled by Excited-State Redox ChemistryR35GM134893 · NIGMS · PRINCETON UNIVERSITY · PI Robert R Knowles · 2020 to 2026
$3.8M
Coupled Protons and Electrons in Biological SystemsR35GM139449 · NIGMS · YALE UNIVERSITY · PI HAMMES-SCHIFFER, SHARON · 2021 to 2025
$2.1M
NIGMS NIH HHS R35 GM134893NIGMS NIH HHS R35 GM139449
6 · The paper itself

Abstract

The design of catalysts capable of functionalizing unactivated C(sp

Identifiers

PMID40492823
PMCPMC12237436

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.