ArticleACS organic & inorganic Au2025
Ligand-Free Cerium-Catalyzed Decarboxylative Fluorination of Carboxylic Acids.
Article in ACS organic & inorganic Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Non-decarboxylative C-H Fluorination of Carboxylic Acids by Iridium Photocatalysis.Organic letters · 2026Article
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3 authors.
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Abstract
We report a ligand-free, cerium-catalyzed decarboxylative fluorination of carboxylic acids via photoinduced ligand-to-metal charge transfer (LMCT) catalysis. This method utilizes readily available carboxylic acids as radical precursors, enabling the selective formation of alkyl fluorides under mild conditions. The protocol tolerates diverse carboxylic acids with a high functional group tolerance. Mechanistic studies confirm that the reaction proceeds via alkyl radical generation through light-induced LMCT of cerium-(IV) carboxylate followed by fluorine transfer. This efficient and cost-effective strategy provides a sustainable route to fluorinated molecules relevant to pharmaceuticals and agrochemicals.
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