Evidence map›Paper›PMID 40486245›Full record

ArticleCarbon future2024

Effective electrochemical trichloroethylene removal from water enabled by selective molecular catalysis.

Yuanzuo Gao, Wanyu Zhang, Chungseok Choi, Bo Shang, Seonjeong Cheon, Aidan Francis Meese, Jae-Hong Kim, Donghui Long, John Fortner, Hailiang Wang

Abstract read
In one paragraph

Article in Carbon future, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Yuanzuo GaoDepartment of Chemistry, Yale University, New Haven, CT 06520, USA.
Wanyu ZhangDepartment of Chemistry, Yale University, New Haven, CT 06520, USA.
Chungseok ChoiDepartment of Chemistry, Yale University, New Haven, CT 06520, USA.
Bo ShangDepartment of Chemistry, Yale University, New Haven, CT 06520, USA.
Seonjeong CheonDepartment of Chemistry, Yale University, New Haven, CT 06520, USA.
Aidan Francis MeeseDepartment of Chemical and Environmental Engineering, Yale University, New Haven, CT 06520, USA.
Jae-Hong KimDepartment of Chemical and Environmental Engineering, Yale University, New Haven, CT 06520, USA.
Donghui LongState Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China.
John FortnerDepartment of Chemical and Environmental Engineering, Yale University, New Haven, CT 06520, USA.
Hailiang WangDepartment of Chemistry, Yale University, New Haven, CT 06520, USA.

Funding

Superfund Training CoreP42ES023716 · NIEHS · UNIVERSITY OF LOUISVILLE · PI SRIVASTAVA, SANJAY · 2017 to 2025
$18.1M
NIEHS NIH HHS P42 ES023716
6 · The paper itself

Abstract

Electrochemistry can provide a viable and sustainable way to treat water polluted by chlorinated volatile organic compounds. However, the removal and valorization of trichloroethylene (TCE) remains as a challenge due to the lack of suitable electrocatalysts with high selectivity and activity. We herein present a catalyst, comprising cobalt phthalocyanine (CoPc) molecules assembled onto multiwalled carbon nanotubes (CNTs), that can electrochemically decompose aqueously dissolved TCE into ethylene and chloride ions at record high rates with close to 100% Faradaic efficiency. Kinetics studies reveal that the rate-determining step is the first electron transfer without proton involvement. We further show that replacing the CNT support with reduced graphene oxide (rGO) can improve the TCE treatment efficacy because of the two-dimensional nanostructure of rGO and its stronger interaction with CoPc molecules. Incorporating the CoPc/rGO catalyst into an electrified membrane filtration device, we demonstrate 95% TCE removal from simulated water samples with environmentally relevant TCE and electrolyte concentrations.

Indexed as

electrified membraneelectrocatalysistrichloroethylenewater treatment

Identifiers

PMID40486245
PMCPMC12143162

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.