ArticleScience advances2025
Air-stable n-type dopant for organic semiconductors via a single-photon catalytic process.
Article in Science advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The trial behind it
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Who cites it
4 citing papers in PubMed.
- Solvent-Guided Chiral Assemblies and Chemical Doping of OEG-Functionalized Conjugated Polymers.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- New-Era Polymer Thermoelectrics: Material Innovations, Doping Frontiers, Decoupling Strategies, and Unconventional Applications.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Counterion-Controlled Photocatalytic Doping of Organic Semiconductors.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Photoinduced Radical Cations Enable Anti-Kasha Emission in a Pyrene-Based Azacationic Ladder Polymer.Small science · 2026Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Controlled doping of conjugated polymer-based semiconductors is crucial for optoelectronic applications. While p-type doping of conjugated polymers can be readily achieved with a variety of oxidants, n-type doping is more challenging, usually requiring highly reactive reducing agents. Here, we demonstrate that an air-stable photoredox catalyst (acridinium salt), together with a mild and air-stable reducing agent (amine), can effectively dope common n-type conjugated polymers under light at room temperature, yielding conductivity values on par with the highest obtained via other means. We elucidate the mechanism and show that this photoredox n-doping occurs via a one-photon-one-electron transfer process that is catalytic in nature. This simple and facile n-doping approach opens more avenues for doping organic semiconductors with the potential to revolutionize device design and substantially enhance doping efficiency.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.