Evidence map›Paper›PMID 40474414›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Harnessing Bifunctional N-Benzoyloxyamides for Photoredox Amidative Dual Functionalizations of Alkenes.

Harin Ryoo, Hyeyun Keum, Dongwook Kim, Sukbok Chang

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Harin Ryoo *Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea.ORCID https://orcid.org/0009-0007-9359-7502
Hyeyun Keum *Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea.ORCID https://orcid.org/0000-0001-8508-9259
Dongwook KimDepartment of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea.ORCID https://orcid.org/0000-0003-4432-371X
Sukbok ChangDepartment of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea.ORCID https://orcid.org/0000-0001-9069-0946

Funding

Institute for Basic Science IBS-R10-D1
6 · The paper itself

Abstract

Here, we present a photocatalytic strategy for the intermolecular dual functionalizations of alkenes using N─O bifunctional reagents in an atom-economical fashion. By leveraging N-benzoyloxyamides as bifunctional precursors for generating both amidyl radical and internal O-nucleophiles, this approach achieves chemoselective olefin amidation with simultaneous incorporation of additional functional groups. The current method readily accesses a range of doubly functionalized amino products through 1,2-amidooxygenation, amidoazidation, and formal anti-Markovnikov hydroamidation. Mechanistic studies revealed that the selective interplay of radical and ionic pathways is operative to enable a unified platform for this olefin dual functionalization.

Indexed as

Amidyl radicalBifunctional N─O reagentOlefin amido‐functionalizationsPhotocatalysisRadical reactions

Identifiers

PMID40474414
PMCPMC12322644

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.