ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
Confinement-Induced Metastable Supramolecular Assembly: Dynamic Built-in Electric Field Driving Deep Mineralization of Organic Pollutants.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
1 citing paper in PubMed.
- Confinement-Induced Metastable Supramolecular Assembly: Dynamic Built-in Electric Field Driving Deep Mineralization of Organic Pollutants.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Constructing built-in electric fields (IEF) in homomeric supramolecular assembly (SA) offers an exciting research avenue. To boost dipole, the introduction of a functional side chain in the monomer is essential. Unfortunately, this disrupts the monomer planarity, inevitably increasing intermolecular distance, which is contradictory to achieving high IEF. Here, by means of the confinement of layered double hydroxide (LDH), various monomers (naphthalene and perylene diimide derivatives) successfully form metastable SA with smaller intermolecular distances than in crystals. The IEF enhancement value can reach 11.8 times, enabling a 71.52% charge separation efficiency and a 78.10% total organic carbon (TOC) removal rate in phenol degradation, presenting state-of-the-art results. Mechanism elucidates LDH confinement overcomes the energy barrier associated with the ordered and close packing of monomers, moving monomer away from the thermodynamic equilibrium state. The universality of this approach will pave the way for exploring other multifunctional monomers, thereby fostering advancement in material science, chemical synthesis, and photo-conversion.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.