Evidence map›Paper›PMID 40462521›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Self-Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C─F and C─O Bond Cleavage.

Aleksandr Sorvanov, Shubham Deolka, Eugene Khaskin, Robert R Fayzullin, Serhii Vasylevskyi, Julia R Khusnutdinova

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Aleksandr SorvanovCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.ORCID https://orcid.org/0000-0003-4117-0674
Shubham DeolkaCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.ORCID https://orcid.org/0000-0002-0050-0780
Eugene KhaskinCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.ORCID https://orcid.org/0000-0003-1790-704X
Robert R FayzullinArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 8 Arbuzov Street, Kazan, 420088, Russian Federation.ORCID https://orcid.org/0000-0002-3740-9833
Serhii VasylevskyiCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.ORCID https://orcid.org/0000-0001-6219-6051
Julia R KhusnutdinovaCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan.ORCID https://orcid.org/0000-0002-5911-4382

Funding

JSPS Kakenhi 23K04743
6 · The paper itself

Abstract

Using a combination of metal-promoted reactivity, in situ covalent bond modification, and hydrogen bonding-promoted fluorine labilization, a unified approach was developed to self-assemble a library of customizable ligand architectures directly at the nickel center via selective cleavage of C─F or C─O bonds and the formation of C─C or C─N bonds. As a result, a structurally diverse set of nickelacarbatrane and pincer complexes was obtained, including unsymmetrical and mixed-heterocyclic atranes and trifluoromethylated pincers that cannot be accessed by conventional organic synthetic methods or require multiple steps and a tedious and low-yielding separation. This suggests a possibility of a spontaneous generation of high-complexity structures from a commonly used metal precursor and simple N-heterocycle building blocks, despite commonly believed innocence of the C─F bonds, which may also generate catalytically active species.

Indexed as

AtraneC─F bond activationC─O bond activationNickelSelf‐assembly

Identifiers

PMID40462521
PMCPMC12322642

What OpenQuestion holds

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LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.