Evidence map›Paper›PMID 40457857›Full record

ArticleOrganic letters2025

Elucidation of a Parasitic Proton-Coupled Electron Transfer in a Photocatalytic Benzylic C-H Sulfonamidation.

Nicholas A Fitzpatrick, Anna M Howarth, Grzegorz J Skrzypek, Jisun Lee, Hatice G Yayla, Patricia Z Musacchio

Abstract read
In one paragraph

Article in Organic letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Nicholas A FitzpatrickWorcester Polytechnic Institute, 100 Institute Road, Worcester, Massachusetts 01609, United States.
Anna M HowarthNatural Sciences Complex, The State University of New York at Buffalo, Buffalo, New York 14260, United States.
Grzegorz J SkrzypekNatural Sciences Complex, The State University of New York at Buffalo, Buffalo, New York 14260, United States.
Jisun LeeMedicine Design, Pfizer Research and Development, 445 Eastern Point Road, Groton, Connecticut 06340, United States.ORCID 0000-0003-1750-0063
Hatice G YaylaMedicine Design, Pfizer Research and Development, 445 Eastern Point Road, Groton, Connecticut 06340, United States.
Patricia Z MusacchioWorcester Polytechnic Institute, 100 Institute Road, Worcester, Massachusetts 01609, United States.ORCID 0000-0002-0211-1893

Funding

Mild Strategies in the Direct Generation of Carbocation Intermediates from C(sp3)–H Bonds.R35GM147021 · NIGMS · WORCESTER POLYTECHNIC INSTITUTE · PI Patricia Zhang Musacchio · 2022 to 2026
$2.0M
NIGMS NIH HHS R35 GM147021
6 · The paper itself

Abstract

Strategies for C-H amination with sulfonamides have been dominated by stoichiometric strategies or Rh/Cu catalysis using strong oxidants, elevated temperatures, or excess equivalents of C-H partner. We developed a photocatalytic C-H amination with a bench-stable

Identifiers

PMID40457857
PMCPMC12239669

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.