ArticleJournal of the American Chemical Society2025
Theoretical Insights into the Resonant Suppression Effect in Vibrational Polariton Chemistry.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- A macroscopic condensation theory for vibrational strong coupling effects.Nature communications · 2026Article
- Quantum Dynamics Simulations of Polariton Transport in a Bloch Surface Wave Cavity.Nanophotonics (Berlin, Germany) · 2026Article
- Validating free spectral range tracking as a robust method for mitigating artifacts in VSC kinetics.RSC advances · 2026Article
- Resonant Enhancement of Photolysis through Plasmon-Vibrational Coupling.Journal of the American Chemical Society · 2026Article
- Polaritonic Control of Blackbody Infrared Radiative Dissociation.The journal of physical chemistry letters · 2025Article
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Authors and funding
3 authors.
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Abstract
Recent experiments demonstrated the possibilities of modifying ground-state chemical reaction rates by placing an ensemble of molecules in an optical microcavity through a resonant coupling between the cavity mode and molecular vibrations. Typical VSC experiments operate in the absence of any light source. The VSC-induced rate constant suppression occurs under the resonance condition when the cavity frequency matches the molecular vibrational frequency, and only under the normal incidence when considering in-plane momentum inside a Fabry-Pérot cavity. In this work, we use quantum dynamics simulations and analytic theories to provide valuable insights into observed VSC phenomena, including the resonance behavior, the nonlinear change of the rate constant when increasing Rabi splitting, modification of both reactive enthalpy and entropy, and a reason why, with a very low barrier, there is a lack of the cavity modification. The analytic theory also exhibits the normal incidence condition and collective coupling effects.
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