ArticleACS central science2025
Unexpected Damage on Metal Artifacts Triggered by the Hazardous Interfacial Interaction from Aging of Polymer Coatings.
Article in ACS central science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
1 citing paper in PubMed.
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Polymer coatings are currently being employed for preservation of metal artifacts. However, there is insufficient awareness that inevitable aging of polymer coatings is bound to damage metal artifacts due to the lack of a direct and sensitive methodology to study the aging behaviors of polymers coated on the artifacts. Herein, we have developed an in situ and three-dimensional strategy to visualize the early stage aging behaviors of polymers coated on metal artifacts by lighting carboxyl groups generated from polymer aging. It is disclosed that polymer aging occurred simultaneously at the surface and the interface with metal artifacts, generating carboxyl groups and hydroxyl radicals to induce the corrosion and oxidation of metallic artifacts. In turn, the generated metallic ions could further aggravate the aging of polymer coatings, manifested as the larger volume of the aged sites at the interface with metal artifacts in comparison with that at the surface of polymer coatings. Such a circular reaction is validated using real metal artifact samples. These findings raised a timely alarm for the conservation ability and potential threat of polymer coatings on metal artifacts. It is anticipated that the proposed strategy could provide solid supports for the implementation of advanced conservation strategies for metal artifacts.
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Registered trials
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