Evidence map›Paper›PMID 40450028›Full record

ArticleNature communications2025

Timing the escape of a photoexcited electron from a molecular cage.

Connor Fields, Aleksandra Foerster, Sadegh Ghaderzadeh, Ilya Popov, Bang Huynh, Filipe Junqueira, Tyler James, Sofia Alonso Perez, David A Duncan, Tien-Lin Lee and 10 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Ultrafast chemistry.Communications chemistry · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

20 authors.

Connor FieldsSchool of Physics & Astronomy, University of Nottingham, Nottingham, UK.
Aleksandra FoersterSchool of Chemistry, University of Nottingham, Nottingham, UK.
Sadegh GhaderzadehSchool of Chemistry, University of Nottingham, Nottingham, UK.ORCID http://orcid.org/0000-0003-4416-7147
Ilya PopovSchool of Chemistry, University of Nottingham, Nottingham, UK.
Bang HuynhSchool of Chemistry, University of Nottingham, Nottingham, UK.ORCID http://orcid.org/0000-0002-5226-4054
Filipe JunqueiraSchool of Physics & Astronomy, University of Nottingham, Nottingham, UK.
Tyler JamesSchool of Physics & Astronomy, University of Nottingham, Nottingham, UK.ORCID http://orcid.org/0000-0002-9681-1558
Sofia Alonso PerezSchool of Physics & Astronomy, University of Nottingham, Nottingham, UK.
David A DuncanSchool of Chemistry, University of Nottingham, Nottingham, UK.ORCID http://orcid.org/0000-0002-0827-2022
Tien-Lin LeeDiamond Light Source, Harwell Science & Innovation Campus, Didcot, UK.ORCID http://orcid.org/0000-0001-6935-5983
Yitao WangSchool of Physics & Astronomy, University of Nottingham, Nottingham, UK.
Sally BloodworthSchool of Chemistry and Chemical Engineering, University of Southampton, Southampton, UK.ORCID http://orcid.org/0000-0003-2219-3635
Gabriela HoffmanSchool of Chemistry and Chemical Engineering, University of Southampton, Southampton, UK.
Mark WalkeySchool of Chemistry and Chemical Engineering, University of Southampton, Southampton, UK.
Richard J WhitbySchool of Chemistry and Chemical Engineering, University of Southampton, Southampton, UK.
Malcolm H LevittSchool of Chemistry and Chemical Engineering, University of Southampton, Southampton, UK.ORCID http://orcid.org/0000-0001-9878-1180
Brian KiralySchool of Physics & Astronomy, University of Nottingham, Nottingham, UK.ORCID http://orcid.org/0000-0002-4666-9290
James N O'SheaSchool of Physics & Astronomy, University of Nottingham, Nottingham, UK.
Elena BesleySchool of Chemistry, University of Nottingham, Nottingham, UK. elena.besley@nottingham.ac.uk.ORCID http://orcid.org/0000-0002-9910-7603
Philip MoriartySchool of Physics & Astronomy, University of Nottingham, Nottingham, UK. philip.moriarty@nottingham.ac.uk.ORCID http://orcid.org/0000-0002-9926-9004

Funding

Diamond Light Source SI- SI-31574-1, SI31574-2, and SI-31574-3Diamond Light Source STU0425EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) 786707RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/M001962/1RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/P009980/1RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/ T022108/1RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/T033568/1RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/V000055/1RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/X012883/1Royal Society Wolfson Research Fellowship
6 · The paper itself

Abstract

Charge transfer is fundamentally dependent on the overlap of the orbitals comprising the transport pathway. This has key implications for molecular, nanoscale, and quantum technologies, for which delocalization (and decoherence) rates are essential figures of merit. Here, we apply the core hole clock technique-an energy-domain variant of ultrafast spectroscopy-to probe the delocalization of a photoexcited electron inside a closed molecular cage, namely the Ar 2p

Identifiers

PMID40450028
PMCPMC12126515

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.