Evidence map›Paper›PMID 40442248›Full record

ArticleNature chemistry2025

Bidentate N-ligand-assisted gold redox catalysis with hydrogen peroxide.

Hongwei Shi, Matthias Rudolph, Jun Li, Yu Tian, Martin C Dietl, Hadil Alshurafa, Yaowen Liu, Tao Wang, Henrik Habeck, Philipp M Stein and 5 more

Abstract read
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Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

15 authors.

Hongwei ShiOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Matthias RudolphOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Jun LiOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.ORCID http://orcid.org/0000-0001-8524-4634
Yu TianOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Martin C DietlOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Hadil AlshurafaOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Yaowen LiuOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Tao WangOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Henrik HabeckOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.ORCID http://orcid.org/0009-0002-5071-0476
Philipp M SteinOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Petra KrämerOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Frank RomingerOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Thomas OeserOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany.
Ning JiaoState Key Laboratory of Natural and Biomimetic Drugs, Chemical Biology Center, School of Pharmaceutical Sciences, Peking University, Beijing, China. jiaoning@pku.edu.cn.ORCID http://orcid.org/0000-0003-0290-9034
A Stephen K HashmiOrganisch-Chemisches Institut, Heidelberg University, Heidelberg, Germany. hashmi@hashmi.de.ORCID http://orcid.org/0000-0002-6720-8602

Funding

China Postdoctoral Science Foundation GZC20230165National Natural Science Foundation of China (National Science Foundation of China) 22293014, 22131002, T2450076National Natural Science Foundation of China (National Science Foundation of China) 22401010
6 · The paper itself

Abstract

Gold redox catalysis, which exploits the ability of strong π-acid activation in combination with redox reactions, has emerged as an attractive synthetic method with unique reactivities compared to other transition metals. However, gold redox chemistry bears the challenge to overcome the high redox potential of Au(I)/Au(III) (1.41 V). The classical strategy of gold redox catalysis applies strong external chemical oxidants which inevitably results in low atom economy and substrate limitations due to incompatibility with functional groups. Here we report a bidentate N-ligand (for example, Phen, Bpy) assisted gold redox catalysis using H

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.