Evidence map›Paper›PMID 40442067›Full record

ArticleNature communications2025

Oxygen-doped carbon-supported palladium nanoparticles boost the tandem hydrogenation-acetalization-hydrogenolysis of phenols and diphenyl ethers to cyclohexyl ethers.

Lang Jiang, Xiang Li, Yiqian Ma, Yiliang Hua, Yicheng Peng, Mengxiang Ma, Chengxiang Shi, Jun Wang, Ji-Jun Zou, Qiang Deng

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Lang Jiang *School of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang, P. R. China.
Xiang Li *College of Forestry, Jiangxi Agricultural University, No. 1101 Zhimin Avenue, Nanchang, P. R. China.
Yiqian MaSchool of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang, P. R. China.
Yiliang HuaSchool of Future Technology, Nanchang University, No. 999 Xuefu Avenue, Nanchang, P. R. China.
Yicheng PengSchool of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang, P. R. China.
Mengxiang MaSchool of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang, P. R. China.
Chengxiang ShiSchool of Chemical Engineering and Technology, Tianjin University, Tianjin, P. R. China.
Jun WangSchool of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang, P. R. China.ORCID http://orcid.org/0000-0001-5176-309X
Ji-Jun ZouSchool of Chemical Engineering and Technology, Tianjin University, Tianjin, P. R. China.ORCID http://orcid.org/0000-0002-9126-1251
Qiang DengSchool of Chemistry and Chemical Engineering, Nanchang University, No. 999 Xuefu Avenue, Nanchang, P. R. China. dengqiang@ncu.edu.cn.ORCID http://orcid.org/0000-0003-0664-5419

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22308135National Natural Science Foundation of China (National Science Foundation of China) 52162014
6 · The paper itself

Abstract

The one-pot hydrotreatment of phenols to cyclohexyl ethers is crucial but difficult to achieve for fine chemical synthesis owing to the easy overhydrogenation to cyclohexanols over traditional metal-acid bifunctional catalysts. Herein, surface oxygen-doped carbon-supported Pd nanoparticles (Pd/C-O) were prepared via nitric acid oxidation and subsequent incipient wetness impregnation, demonstrating the tandem hydrogenation-acetalization-hydrogenolysis route of phenol to cyclohexyl methyl ether, achieving an significant yield of 97.9% in a methanol solvent at a low temperature of 110 °C. Catalytic mechanism investigation indicated that the in situ hydrogen spillover from Pd nanoparticles to the Pd-O-C interface formed H

Identifiers

PMID40442067
PMCPMC12123032

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.