Evidence map›Paper›PMID 40441899›Full record

ArticleMacromolecular rapid communications2025

Experimental and Analytical Tools for the Chemical Recycling of Engineering Plastics - A Multi-Scale Pyrolysis Study on Polydicyclopentadiene.

Michael Zeller, Salar Tavakkol, Dieter Stapf

Abstract read
In one paragraph

Article in Macromolecular rapid communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Michael ZellerInstitute for Technical Chemistry, Karlsruhe Institute of Technology, Kaiserstrasse 12, 76131, Karlsruhe, Germany.ORCID https://orcid.org/0000-0002-9899-2110
Salar TavakkolInstitute for Technical Chemistry, Karlsruhe Institute of Technology, Kaiserstrasse 12, 76131, Karlsruhe, Germany.ORCID https://orcid.org/0000-0001-5142-2439
Dieter StapfInstitute for Technical Chemistry, Karlsruhe Institute of Technology, Kaiserstrasse 12, 76131, Karlsruhe, Germany.ORCID https://orcid.org/0000-0001-6499-062X

Funding

Helmholtz Association
6 · The paper itself

Abstract

The creation of a circular economy for plastics is essential for a sustainable future. Currently, established recycling processes are not universally applicable. Pyrolysis can complement current recycling through the conversion of complex plastic wastes to condensates and gases for reintroduction into chemical industry processes. A multi-scale approach for the characterization of pyrolysis properties is presented using the example of polydicyclopentadiene. Pyrolysis-GC-MS (µg-scale), thermogravimetric (mg-scale), and lab-scale (g-scale) pyrolysis investigations are complemented by high-resolution product analytics. In Py-GC-MS, 1,3-cyclopentadiene is abundant, hinting at depolymerization as a dominant decomposition mechanism. In thermogravimetry, approx. 20 mass-% of the sample is converted to solids. On lab-scale, secondary reactions influence the product yield and spectrum significantly, indicated by a solid yield of ≈40 mass-%. Polydicyclopentadiene exhibits a broad product spectrum comprising unsaturated hydrocarbons and aromatics. In the condensed product, no 1,3-cyclopentadiene is detected, indicating recombination or derivatization reactions. Significant solid residue formation emphasizes scaling effects. The employed analytics provide comprehensive analyses of condensed and non-condensed products. With the presented approach, primary and secondary mechanisms can be resolved and crucial process parameters identified. In this way, a powerful toolset for the development of robust pyrolysis processes that aid in achieving circularity for plastics is provided.

Indexed as

CyclopentanesPlasticsPolymersRecyclingGas Chromatography-Mass SpectrometryPyrolysisThermogravimetryCyclopentanesPlasticsPolymerschemical recyclingcircular economygas chromatographypolydicyclopentadienepyrolysisthermogravimetry

Identifiers

PMID40441899
PMCPMC12687674

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.