ArticlePolymers2025
Silicon-Containing π-Conjugated Schiff Base Oligomers with Naphthalene or Binaphthalene Moieties in the Backbone: Synthesis and Study of Properties.
Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Four silane-containing Schiff base oligomers (o-SBNs and o-SBBs) were synthesized by high-temperature polycondensation reactions using silicon-based dialdehydes with naphthalene and 1,1'-binaphthalene diamine derivates. The samples showed a moderate solubility in common organic solvents, where the incorporation of TPS cores into o-SBN2 allows the formation of highly soluble material in non-polar solvents with higher molecular weights (11.58 kDa) and polydispersity. All oligo-SBs displayed high thermal resistance (above 450 °C), showing enhanced thermal stability for TPS-containing oligomers, with the degradation temperature exceeding 530 °C (o-SBB2) and high T
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