Evidence map›Paper›PMID 40420625›Full record

ArticleChemistry, an Asian journal2025

Seven-Coordinate Ruthenium Complex with an SiNN-Pincer Ligand as a Catalyst for Vinyl C─H Deuteration of Olefins.

Takashi Komuro, Daiki Mochizuki, Nozomu Ishiwata, Hiromi Tobita, Hisako Hashimoto

Abstract read
In one paragraph

Article in Chemistry, an Asian journal, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Takashi KomuroDepartment of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan.
Daiki MochizukiDepartment of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan.
Nozomu IshiwataDepartment of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan.
Hiromi TobitaDepartment of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan.
Hisako HashimotoDepartment of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan.ORCID https://orcid.org/0000-0001-9649-0857

Funding

JSPS KAKENHI JP19K05490JSPS KAKENHI JP22H02088JSPS KAKENHI JP22K05123
6 · The paper itself

Abstract

Seven-coordinate ruthenium complexes 1a and 1b, featuring silyl-2,2´-bipyridine SiNN-pincer ligands with i-Pr and t-Bu groups on Si, respectively, were synthesized. Their capped octahedral structures were revealed by single-crystal X-ray diffraction study. The stoichiometric reactions of 1a and 1b with styrene in THF afforded η

Indexed as

CatalysisC─H deuterationPincer ligandRutheniumSilyl group

Identifiers

PMID40420625
PMCPMC12392715

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.