ArticleRSC advances2025
Thermal deprotection: a sustainable and efficient strategy for synthesising α-polylysine adsorbents.
Article in RSC advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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2 authors.
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Abstract
α-Polylysine (PLys) is a versatile, renewable, and biodegradable polymer with extensive amine functionality and water-solubility, making it an ideal candidate for critical applications such as heavy metal adsorption and beyond. However, conventional synthesis of linear PLys relies on toxic reagents for side-chain deprotection, raising environmental and safety concerns that hinder its commercial scalability and sustainability. In this work, we introduce a groundbreaking, environmentally friendly method for PLys production using thermal deprotection of fluorenylmethyloxycarbonyl (Fmoc)-protected PLys. This innovative approach eliminates the need for hazardous deprotection agents, offering a greener and more cost-effective alternative. Beyond the synthesis of homopolymeric PLys, we extend this method to create α-polylysine-
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