Evidence map›Paper›PMID 40405709›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Tailored Crystallization Dynamics for Efficient and Stable DMSO-Free Tin Perovskite Solar Cells.

Shengnan Zuo, Alexander Tarasov, Lennart Frohloff, Karunanantharajah Prashanthan, Florian Ruske, Mailis Lounasvuori, Chiara Frasca, André Dallmann, Fengshuo Zu, Florian Mathies and 13 more

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Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

23 authors.

Shengnan ZuoHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Active Materials and Interfaces for Stable Perovskite Solar Cells (SE-AMIP), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0009-0005-4842-9871
Alexander TarasovHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Solution Processing of Hybrid Materials & Devices (SE-ALM), Kekuléstraße 5, 12489, Berlin, Germany.
Lennart FrohloffHumboldt University of Berlin, Department of Physics, Brook-Taylor-Straße 6-BT6, 12489, Berlin, Germany.
Karunanantharajah PrashanthanHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Spins in Energy Conversion and Quantum Information Science (SE-ASPIN), Hahn-Meitner-Platz 1, 14109, Berlin, Germany.ORCID https://orcid.org/0000-0001-6042-7055
Florian RuskeHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Active Materials and Interfaces for Stable Perovskite Solar Cells (SE-AMIP), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-6363-4591
Mailis LounasvuoriHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Young Investigator Group Nanoscale Solid-Liquid Interfaces, Hahn-Meitner Platz 1, 14109, Berlin, Germany.
Chiara FrascaHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Active Materials and Interfaces for Stable Perovskite Solar Cells (SE-AMIP), Kekuléstraße 5, 12489, Berlin, Germany.
André DallmannHumboldt University of Berlin, Institude of Chemistry, Brook-Taylor-Str. 2, 12489, Berlin, Germany.
Fengshuo ZuHumboldt University of Berlin, Department of Physics, Brook-Taylor-Straße 6-BT6, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-5861-4887
Florian MathiesHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Solution Processing of Hybrid Materials & Devices (SE-ALM), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-8950-3901
Florian SchelerHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Perovskite Tandem Solar Cells (SE-APET), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0001-5066-3206
Noor Titan Putri HartonoHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Active Materials and Interfaces for Stable Perovskite Solar Cells (SE-AMIP), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-0748-0620
Guixiang LiHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Active Materials and Interfaces for Stable Perovskite Solar Cells (SE-AMIP), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-8730-0713
Jinzhao LiHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Solution Processing of Hybrid Materials & Devices (SE-ALM), Kekuléstraße 5, 12489, Berlin, Germany.
Maxim SimmondsHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Solution Processing of Hybrid Materials & Devices (SE-ALM), Kekuléstraße 5, 12489, Berlin, Germany.
Wenhui LiInstitute of Chemical Research of Catalonia (ICIQ-CERCA), Avda. Països Catalans, 16, 43007, Tarragona, Spain.
Norbert KochHumboldt University of Berlin, Department of Physics, Brook-Taylor-Straße 6-BT6, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-6042-6447
Steve AlbrechtHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Perovskite Tandem Solar Cells (SE-APET), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0001-9962-9535
Meng LiKey Laboratory for Special Functional Materials of Ministry of Education, Henan University, 475004, Kaifeng, P. R. China.
Eva UngerHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Solution Processing of Hybrid Materials & Devices (SE-ALM), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-3343-867X
Mahmoud Hussein AldanmasyHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Active Materials and Interfaces for Stable Perovskite Solar Cells (SE-AMIP), Kekuléstraße 5, 12489, Berlin, Germany.
Artem MusiienkoHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Young Investigator Group, Robotized Material and Photovoltaic Engineering, Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-2259-8387
Antonio AbateHelmholtz-Zentrum Berlin für Materialien und Energie GmbH, Department Active Materials and Interfaces for Stable Perovskite Solar Cells (SE-AMIP), Kekuléstraße 5, 12489, Berlin, Germany.ORCID https://orcid.org/0000-0002-3012-3541

Funding

China Scholarship Council 202104910130Deutscher Akademischer Austauschdienst 57381412European Union's Framework Program for Research and Innovation HORIZON EUROPE 101061809German Federal Ministry of Education and Research 03XP0625Zeitenwende - Zukunftstechnologie Tandem Solarzellen
6 · The paper itself

Abstract

Tin perovskite solar cells are emerging as a sustainable lead-free alternative in thin film photovoltaics. DMSO-free processed tin perovskites are gaining interest due to the detrimental effects of DMSO on tin oxidation. However, replacing DMSO with other solvents remains challenging due to the accelerated crystallization dynamics in non-DMSO systems. In this study, the crystallization process in a DMSO-free solvent system is regulated by managing the transition from the sol-gel phase to the solid film. Specifically, piperazine dihydriodide (PDAI) and 4-tert-butylpyridine (tBP) are utilized to coordinately tune the colloidal chemistry through forming large pre-nucleation clusters in perovskite ink, further, facilitating the film formation process. By combining tBP and PDAI, a controllable crystallization rate is achieved as evidenced by in situ photoluminescence (PL) measurement during spin-coating. As a result, tin perovskite films show high crystallinity and improved microstructure. Devices treated with tBP+PDAI exhibit a champion power conversion efficiency of 7.8% and excellent stability without observable degradation for over 3000 h stored in the N

Indexed as

crystallizationDMSO‐freein situ PLtin perovskites

Identifiers

PMID40405709
PMCPMC12362759

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