ArticleAngewandte Chemie (International ed. in English)2025
Hydrogen Bond-Assisted PCET and Formation of W
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
2 citing papers in PubMed.
- Redox-Active Tungsten Mono-Oxo Bis(dithiolene) Complex: A Fast-Rechargeable Anode for High-Capacity Lithium-Ion Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Hydrogen Bond-Assisted PCET and Formation of WAngewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
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Authors and funding
10 authors.
Funding
Abstract
The redox non-innocent nature of dithiolene ligands is well known for stabilizing high-valent metal ions and facilitating proton-coupled electron transfer (PCET) processes. Until now, proton reactivity at the dithiolene site has been primarily associated with low-valent metal centers, as high-valent metal-dithiolene complexes were not considered viable for such reactivity. This study introduces high-valent bis(dithiolene) tungsten (W)-oxo complexes featuring hydrogen-bonding interactions, unveiling a novel proton reduction mechanism mediated by the dithiolene moiety. The process begins with a nucleophilic W-oxo, forming a hydrogen bond, followed by a second hydrogen bond at the dithiolene-sulfur (S) site. These hydrogen-bonding interactions significantly modulate the molecular orbital energy levels, enabling the W
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Registered trials
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