Evidence map›Paper›PMID 40396867›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

Dinuclear Copper Complex with a Pyridazine-Bridged Octadentate Ligand: Monooxygenase Activity and Characterization of Copper-Oxygen Intermediates.

Alexander Stüber, Ramona Jurgeleit, Benjamin Grimm-Lebsanft, Sören Buchenau, Ina Kellner, Yannik Appiarius, Christian Näther, Jan Krahmer, Ivana Ivanović-Burmazović, Michael Rübhausen and 2 more

Abstract read
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In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Alexander StüberInstitute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Straße 2, 24118, Kiel, Germany.ORCID https://orcid.org/0009-0007-9414-2585
Ramona JurgeleitInstitute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Straße 2, 24118, Kiel, Germany.ORCID https://orcid.org/0000-0002-6106-8071
Benjamin Grimm-LebsanftInstitut für Nanostruktur- und Festkörperphysik, Center for Free Electron Laser Science (CFEL), Universität Hamburg, Luruper Chaussee 149, 22761, Hamburg, Germany.ORCID https://orcid.org/0000-0002-4070-3531
Sören BuchenauInstitut für Nanostruktur- und Festkörperphysik, Center for Free Electron Laser Science (CFEL), Universität Hamburg, Luruper Chaussee 149, 22761, Hamburg, Germany.ORCID https://orcid.org/0000-0001-6324-8386
Ina KellnerDepartment Chemie, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, Haus D, 81377, München, Germany.ORCID https://orcid.org/0000-0003-1042-9671
Yannik AppiariusInstitute for Organic and Analytical Chemistry, University of Bremen, Leobener Strasse 7, 28359, Bremen, Germany.ORCID https://orcid.org/0000-0002-9849-6950
Christian NätherInstitute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Straße 2, 24118, Kiel, Germany.ORCID https://orcid.org/0000-0001-8741-6508
Jan KrahmerInstitute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Straße 2, 24118, Kiel, Germany.ORCID https://orcid.org/0000-0002-6895-9985
Ivana Ivanović-BurmazovićDepartment Chemie, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, Haus D, 81377, München, Germany.ORCID https://orcid.org/0000-0002-1651-3359
Michael RübhausenInstitut für Nanostruktur- und Festkörperphysik, Center for Free Electron Laser Science (CFEL), Universität Hamburg, Luruper Chaussee 149, 22761, Hamburg, Germany.ORCID https://orcid.org/0000-0003-3868-392X
Maria A NaumovaDESY, Deutsches Elektronen-Synchrotron (DESY), Notkestrasse 85, 22607, Hamburg, Germany.ORCID https://orcid.org/0000-0001-8473-2716
Felix TuczekInstitute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Straße 2, 24118, Kiel, Germany.ORCID https://orcid.org/0000-0001-7290-9553

Funding

Bundesministerium für Forschung und Technologie 05K19GU5Deutsche Forschungsgemeinschaft RU 773/8-1
6 · The paper itself

Abstract

Copper-containing enzymes catalyze the mono-oxygenation of aromatic and aliphatic substrates in nature. Herein, we report on the synthesis of a new dinuclear copper complex supported by an octadentate ligand with a pyridazine backbone. Low-temperature oxygenation leads to a μ-1,1-hydroperoxo dicopper(II) (Cu

Indexed as

catalysiscopperEXAFS spectroscopymetalloenzymesoxygenation

Identifiers

PMID40396867
PMCPMC12223343

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.