ArticleJournal of the American Chemical Society2025
Molecular Design for Optically Induced Magnetization: Targeting Excited State Orbital Degeneracy in Tungsten(V) Complexes.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- Excited-state orbital angular momentum enables all-optical molecular spin coherence.Chemical science · 2026Article
- Benchmarking Cantilever Torque Magnetometry as a Platform for Characterizing Molecular Qubits: A Case Study on Ni(II) Complexes.Journal of the American Chemical Society · 2026Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The rise of quantum information science has spurred chemists to prepare new molecules that serve as useful building blocks in quantum technologies of the future. Implementation of molecular spin-based qubits requires new methods to induce high spin polarization of samples. Herein, we report design criteria to develop axially symmetric spin-1/2 molecules amenable to optically induced magnetization (OIM), a technique using circularly polarized (CP) excitation to deliver spin polarization. We apply these criteria to develop a series of tungsten(V) chalcogenide complexes that are demonstrated to have large spin-sensitive responses to CP light using magnetic circular dichroism (MCD) that could allow up to ∼20% spin polarization through OIM. Pulsed electron paramagnetic resonance (EPR) spectra reveal these systems have improved relaxation times over molecules like K
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Registered trials
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