Seeing an Unobservable Fe(III)/Fe(IV) Redox Process of the Nonheme Iron N4Py Complex by High-Speed Surface-Enhanced Raman Spectroelectrochemistry.

C Maurits de Roo, W J Niels Klement, Daniel R Duijnstee, Aleksandar Staykov, Wesley R Browne

Abstract read

In one paragraph

Article in Inorganic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Million-Fold Activation of C-H Bonds by Fluorinated Nonheme FeACS catalysis · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

C Maurits de RooMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 3, 9747 AG Groningen, The Netherlands.ORCID 0009-0004-1493-9809

W J Niels KlementMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 3, 9747 AG Groningen, The Netherlands.

Daniel R DuijnsteeMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 3, 9747 AG Groningen, The Netherlands.ORCID 0000-0002-7696-9251

Aleksandar StaykovInternational Institute for Carbon Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Motooka, Nishi-ku, 819-0395 Fukuoka, Japan.ORCID 0000-0003-2572-1317

Wesley R BrowneMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 3, 9747 AG Groningen, The Netherlands.ORCID 0000-0001-5063-6961

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

High-valent iron oxido species, central to many enzymatic and biomimetic catalyzed organic oxidative transformations, can be generated by direct electrochemical oxidation, circumventing high-energy O atom donor reagents. Electrochemical generation necessitates knowledge of the redox potentials involved, which is hindered by the lack of well-defined Fe(III)/Fe(IV) redox waves in the voltammetry of many iron-based catalysts. Hence, other approaches including chemical oxidation and bulk spectro(electro)chemical methods need to be taken. In the case of the well-studied oxidation catalyst,

Identifiers

PMID40391616

DOI10.1021/acs.inorgchem.5c01017

PMCPMC12135866

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