Thioketones as a Simple Route Toward Thioester-Based Materials.

Anne D Fernando Pulle, Hendrik Frisch, Bryan T Tuten

Abstract read

In one paragraph

Article in Macromolecular rapid communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Thioketones as a Simple Route Toward Thioester-Based Materials.Macromolecular rapid communications · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Anne D Fernando PulleSchool of Chemistry and Physics, Queensland University of Technology, 2 George Street, Brisbane, QLD, 4000, Australia.

Hendrik FrischSchool of Chemistry and Physics, Queensland University of Technology, 2 George Street, Brisbane, QLD, 4000, Australia.

Bryan T TutenDepartment of Chemistry and Biochemistry, The University of Texas at Tyler, 3900 University Blvd., Tyler, TX, 75799, USA.ORCID https://orcid.org/0000-0002-5419-7561

Funding

Australian Research Council DE200101788

6 · The paper itself

Abstract

For the first time, thioketones, as effective (thio)carbonyl compounds as a monomer in Passerini multicomponent polymerizations, are demonstrated. The resulting polymer is imbued with functional thioesters directly in the backbone. Additionally, the ease in using thioketone monomers (as opposed to thioaldehyde-based monomers) without the need for tedious workup and purification is highlighted. It is shown that soft matter materials made in this fashion can have their material properties easily tuned. Specifically, it is demonstrated that these polymers can be easily degraded via aminolysis, reduce their glass transition via dynamic trans-thioesterification, or transformed into thermoset materials with the addition of thiols and maleimides via thiol-ene chemistry.

Indexed as

EstersKetonesPolymersSulfhydryl CompoundsMolecular StructurePolymerizationEstersKetonesPolymersSulfhydryl Compoundsmulticomponent chemistrypasserini reactionspolymer chemistrypolymeric materialsthiol chemistry

Identifiers

PMID40384315

DOI10.1002/marc.202500076

PMCPMC12272533

What OpenQuestion holds

Textmetadata

LicenceCC BY-NC

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.