ArticleNature communications2025
Electrochemical synthesis of allenyl silanes and allenyl boronic esters.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Thianthrenium Salts as Aryl Radical Precursors for Direct Arylation of β-Dicarbonyl Compounds via Electrochemical SChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Diastereoselective Synthesis of Axially Chiral Skipped Ene-Allenes Containing a Quaternary Stereocenter by Cyclopropene-Allene Metathesis.Angewandte Chemie (International ed. in English) · 2026Article
- All About the Base: Electrochemical Isomerization of Terminal Propargyl Compounds toward the Synthesis of Allenes and Phenols.Organic letters · 2026Article
- Single Photocatalytic Hydrosilylation of Alkenes for the Synthesis of Bis(silyl) and Silaboryl Alkanes.JACS Au · 2025Article
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Authors and funding
4 authors.
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Abstract
Allenyl silanes and boronates are pivotal building blocks in organic synthesis. Nevertheless, their synthesis requires the manipulation of transition metal or highly reactive species. Hence, the development of more sustainable protocol is highly sought after. Here we show the electrochemical synthesis of allenyl silanes and allenyl boronic esters. This catalyst-free method proceeds under mild reaction conditions. The protocol for the synthesis of allenyl silanes shows an excellent efficiency and a good functional group tolerance. The allenyl silanes are isolated in good yields (28 examples, 45-95% yields) without the use of a transition metal catalyst and under mild reaction conditions. A similar protocol is developed for the synthesis of allenyl boronates, which are obtained in low to moderate yields (13 examples, 5-55% yields). Finally, a mechanism based on an oxidative generation of the silyl and boryl radicals is suggested to access these classes of allenes.
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Registered trials
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