ArticleNature chemistry2025
High-performance recyclable polymers enabled by stereo- and sequence-controlled polymerization.
Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- Chemically Recyclable Polymers: Tunable Performance Enabled by Precision Ring-Opening (Co)polymerization.Precision chemistry · 2026Review
- Precise Structural Design for Chemically Recyclable Polymers.Precision chemistry · 2026Review
- The Impact of Copolymer Molecular Sequence on Electronic Transport.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- COAngewandte Chemie (International ed. in English) · 2026Article
- Stereoselective Ring-Opening Polymerization of Racemic Dithiolactones Assisted by Non-Classical C─H⋯X Interactions.Angewandte Chemie (International ed. in English) · 2026Article
- Circularity in Sequence-Controlled Copolyamides Enabled by Regioselective Enzymatic Hydrolysis.Journal of the American Chemical Society · 2026Article
- Diverse polymers with chemical recyclability via regioirregular polymerization of a single monomer.Nature materials · 2026Article
- Lifecycle of dynamic covalent polar-olefin macrocycles via entropy-driven ring-opening polymerization and closed-loop chemical recycling.National science review · 2025Article
- Spirosalen-scandium catalysts enable the epimerization-tolerant closed-loop circularity of poly(l-lactic acid).National science review · 2025Article
- Synthesis of recyclable polyesters via aNational science review · 2025Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Monomer design strategy has become a powerful tool to access chemically recyclable polymers with desired and diverse properties. The presence of two or multiple stereogenic centres in one monomer offers a new dimension to fine-tune the polymer performance. However, it is still a formidable challenge in synthetic polymer chemistry to achieve precise stereocontrol and sequence control over the polymer microstructure. Here we report a stereo- and sequence-controlled polymerization of 5H-1,4-benzodioxepin-3(2H)-one-based monomers with two stereogenic centres (M) to furnish a series of isoenriched AB diblock polymers P(cis-M)-b-P(trans-M) and ABA triblock polymers P(trans-M)-b-P(cis-M)-b-P(trans-M). Notably, P(cis-M2)
Identifiers
40379978What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.