Evidence map›Paper›PMID 40371460›Full record

ArticleAdvanced materials (Deerfield Beach, Fla.)2025

Acid/Base-Responsive Circularly Polarized Luminescence Emitters with Configurationally Stable Nitrogen Stereogenic Centers.

Pablo García-Cerezo, Marcos D Codesal, Arthur H G David, Laura Le Bras, Seifallah Abid, Xuesong Li, Delia Miguel, Masoud Kazem-Rostami, Benoît Champagne, Araceli G Campaña and 2 more

Abstract read
In one paragraph

Article in Advanced materials (Deerfield Beach, Fla.), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Through-bondJournal of materials chemistry. C · 2026
    Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Pablo García-CerezoDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia de Química Aplicada a Biomedicina y Medioambiente (UEQ), Universidad de Granada (UGR), Avda. Fuente Nueva S/N, Granada, 18071, Spain.ORCID https://orcid.org/0000-0001-5270-1675
Marcos D CodesalDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia de Química Aplicada a Biomedicina y Medioambiente (UEQ), Universidad de Granada (UGR), Avda. Fuente Nueva S/N, Granada, 18071, Spain.ORCID https://orcid.org/0000-0001-9249-1182
Arthur H G DavidDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID https://orcid.org/0000-0002-9275-2343
Laura Le BrasCNRS, Chrono-environnement (UMR 6249), Université Marie et Louis Pasteur, Besançon, F-25000, France.ORCID https://orcid.org/0000-0002-5239-0042
Seifallah AbidDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID https://orcid.org/0000-0002-2472-5888
Xuesong LiDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID https://orcid.org/0000-0002-2794-8390
Delia MiguelNanoscopy-UGR Laboratory. Physical Chemistry Department, UEQ, Faculty of Pharmacy, University of Granada, C. U. Cartuja, Granada, 18071, Spain.ORCID https://orcid.org/0000-0002-7876-3986
Masoud Kazem-RostamiDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID https://orcid.org/0000-0003-4821-5820
Benoît ChampagneLaboratory of Theoretical Chemistry, Namur Institute of Structured Matter (NISM), University of Namur, rue de Bruxelles, 61, Namur, 5000, Belgium.ORCID https://orcid.org/0000-0003-3678-8875
Araceli G CampañaDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia de Química Aplicada a Biomedicina y Medioambiente (UEQ), Universidad de Granada (UGR), Avda. Fuente Nueva S/N, Granada, 18071, Spain.ORCID https://orcid.org/0000-0001-5483-5642
J Fraser StoddartDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID https://orcid.org/0000-0003-3161-3697
Victor BlancoDepartamento de Química Orgánica, Facultad de Ciencias, Unidad de Excelencia de Química Aplicada a Biomedicina y Medioambiente (UEQ), Universidad de Granada (UGR), Avda. Fuente Nueva S/N, Granada, 18071, Spain.ORCID https://orcid.org/0000-0002-6809-079X

Funding

Ministerio de Ciencia, Innovación y Universidades / Agencia Estatal de Investigación PID2020-112906GA-I00Ministerio de Ciencia, Innovación y Universidades / Agencia Estatal de Investigación PID2020-113059GB-C21Ministerio de Ciencia, Innovación y Universidades / Agencia Estatal de Investigación / ERDF, EU PID2021-127521NB-I00Ministerio de Ciencia, Innovación y Universidades / Agencia Estatal de Investigación / ERDF, EU PID2023-146433NB-I00
6 · The paper itself

Abstract

A way to prevent the fast configurational interconversion of tertiary amines is to invoke Tröger's base analogs, which display methano- or ethano-bridged diazocine cores fused to aromatic rings. These derivatives are configurationally stable, even in acidic media when their structures bear ethylene bridges. Here, a two- to three-step synthesis is presented of methano- and ethano-bridged Tröger's base analogs with two peripheral fluorophores, i.e., anthracene, pyrene, and 9,9-dimethylfluorene units. These compounds, possessing two nitrogen stereogenic centers, exhibit good circularly polarized luminescence (CPL) dissymmetry factors (|g

Indexed as

chiroptical switchcircularly polarized luminescenceconfigurationally stable nitrogensfluorophoresTröger's Base

Identifiers

PMID40371460
PMCPMC12288784

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.