Ti-Supported Oxide Coatings Based on MWO

Irina G Tarkhanova, Vladimir M Zelikman, Irina V Lukiyanchuk, Marina S Vasilyeva, Vladimir V Tkachev, Vladimir V Korochentsev, Daria H Shlyk

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Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

7 authors.

Irina G TarkhanovaDepartment of Chemistry, Lomonosov Moscow State University, Leninskiye Gory, 1/3, Moscow 119991, Russia.ORCID 0000-0002-6347-7346

Vladimir M ZelikmanDepartment of Chemistry, Lomonosov Moscow State University, Leninskiye Gory, 1/3, Moscow 119991, Russia.ORCID 0009-0002-6608-8116

Irina V LukiyanchukInstitute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 100-letya Vladivostoka Prosp., 159, Vladivostok 690022, Russia.ORCID 0000-0003-1680-4882

Marina S VasilyevaInstitute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 100-letya Vladivostoka Prosp., 159, Vladivostok 690022, Russia.ORCID 0000-0002-6716-1373

Vladimir V TkachevDepartment of Natural Sciences, Far Eastern Federal University, FEFU Campus 10, Ajax Bay, Russky Island, Vladivostok 690922, Russia.ORCID 0000-0003-1383-1367

Vladimir V KorochentsevInstitute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 100-letya Vladivostoka Prosp., 159, Vladivostok 690022, Russia.

Daria H ShlykInstitute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 100-letya Vladivostoka Prosp., 159, Vladivostok 690022, Russia.ORCID 0000-0003-4247-4872

Funding

Institute of Chemistry FEB RAS State Order project no. FWFN (0205)-2025-0001State Assignment of Lomonosov Moscow State University project No. AAAA-A21-121011590090-7

6 · The paper itself

Abstract

In this study, catalytically active coatings on titanium were synthesized by plasma electrolytic oxidation (PEO) in aqueous electrolytes based on sodium tungstate with the addition of sodium phosphate or sodium borate and chelate complexes of iron, cobalt or nickel. Taking into account the EDX, XPS and XRD data, the oxide-phosphate coatings (PWFe, PWCo, PWNi) contained crystalline titanium oxide and amorphous tungstates and/or phosphates of iron triad metals. Amorphization was facilitated by high phosphorus concentrations (up to 6 at.%). Replacing phosphate with borate in the electrolyte with Ni(II)-EDTA complexes led to the crystallization of WO

Indexed as

denitrogenationdesulfurizationperoxide oxidationplasma electrolytic oxidationtungstates

Identifiers

PMID40363804

DOI10.3390/molecules30091998

PMCPMC12073619

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