ArticleACS applied materials & interfaces2025
Deactivating Symmetry Breaking of a Soft Frank-Kasper Phase via Water-Induced Conformational Ordering of a Shapeshifting Dendritic Amphiphile.
Article in ACS applied materials & interfaces, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- On and Off Deformability of Supramolecular Micelles in the Soft Frank-Kasper σ Phase.The journal of physical chemistry letters · 2026Article
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11 authors.
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Abstract
Water guides biomolecules to their native conformations in a high-dimensional conformational space. To explore a similar role in synthetic self-assembly, a wedge-shaped, shape-shifting dendron (SD) was studied. Cooling from the isotropic melt trapped SD in a metastable Frank-Kasper σ phase with symmetry breaking due to high conformational freedom. In situ SAXS, microbeam SAXS, and ATR-FTIR confirmed that water vapor disrupts supramolecular micelles in the σ phase and unfolds some cone-shaped SD molecules, facilitating improved chain-chain packing and inducing the low-symmetry σ phase to transition into a more symmetric hydrated lamellar (
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