Evidence map›Paper›PMID 40358666›Full record

ArticleJournal of fluorescence2025

Experimental and Theoretical Approach to Estimate Electric Dipole Moments and Analysis of Preferential Solvation, Fluorescence Quenching of 4 NPMB Coumarin Molecule by Steady State Method.

Srinath, Shivakumar Chillargikar, Omnath Patil, S M Hanagodimath

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Article in Journal of fluorescence, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

4 authors.

SrinathDepartment of PG Studies and Research in Physics, Gulbarga University, Kalaburagi, 585 106, Karnataka, India. srinathmore@gmail.com.
Shivakumar ChillargikarDepartment of PG Studies and Research in Physics, Gulbarga University, Kalaburagi, 585 106, Karnataka, India.
Omnath PatilDepartment of PG Studies and Research in Physics, Gulbarga University, Kalaburagi, 585 106, Karnataka, India.
S M HanagodimathDepartment of PG Studies and Research in Physics, Gulbarga University, Kalaburagi, 585 106, Karnataka, India.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The fluorescence and absorption characteristics of coumarin 1-(4-nitro-phenoxymethyl)-benzo[f]-chromen-3-one (4NPMB) at room temperature are examined in a mixture of acetonitrile (ACN) and tetrahydrofuran (THF) as well as in a few pure organic solvents. The influence of pure liquids on spectral characteristics is examined using various theories. Ground and excited state electric dipole moments were computed employing theoretical and Solvatochromic approaches. The redshift and excited electric dipole moment value of a molecule indicates that the molecule has gone through the intermolecular charge transfer (ICT). Kamlet-Taft suggests that the 4NPMB molecule integrates the solvent by its hydrogen bonding parameter rather than the dielectric parameter. From Catalan linear regression, we found that solvent acidity (SA) and the polarizability (SP) of a solvent have much more influence compared to solvent basicity (SB) and di-polarity (SdP) on a molecule. According to the preferential solvation investigation, tetrahydrofuran dominates the system up to the bulk molar fraction of 0.31. Acetonitrile thereafter takes over, as shown by the value of the preferential solvation constant (

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DFTElectric dipole momentSolvation and fluorescence quenching

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