ArticleLangmuir : the ACS journal of surfaces and colloids2025
Cationic and Nonionic Surfactant Micelles in a Halogen-Free Carboxylic Acid-Based Deep Eutectic Solvent.
Article in Langmuir : the ACS journal of surfaces and colloids, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In recent years, it has been shown that deep eutectic solvents (DES) and similar mixtures solvate and allow for self-assembly of surfactants, serving as potential "green" alternatives as solvents for, for example, templating nanomaterials or drug delivery applications. Which surfactants are soluble and how they self-assemble depends strongly on the mixture components and their molar ratio. Here, we present the surfactant behavior in halogen-free citric acid: glycerol-based systems and show how a change in the molar ratio can affect the micellization of cationic surfactants. We also study micellization of nonionic ethylene oxide surfactants, which are insoluble in the most common hydrophilic choline chloride-based DES, such as choline chloride: urea and choline chloride: glycerol, in the absence of water. We find that the cationic C
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