Evidence map›Paper›PMID 40343315›Full record

ArticleRSC advances2025

Electron donor-acceptor complex-driven photocatalyst-free synthesis of nitrocyclopropanes.

Paula Pérez-Ramos, Patrícia I C Godinho, Raquel G Soengas, Humberto Rodríguez-Solla

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in RSC advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Paula Pérez-RamosDepartment of Organic and Inorganic Chemistry, Instituto Universitario de Química Organometálica Enrique Moles, University of Oviedo Julián Clavería 8 33006 Oviedo Spain rsoengas@uniovi.es hrsolla@uniovi.es.
Patrícia I C GodinhoDepartment of Organic and Inorganic Chemistry, Instituto Universitario de Química Organometálica Enrique Moles, University of Oviedo Julián Clavería 8 33006 Oviedo Spain rsoengas@uniovi.es hrsolla@uniovi.es.
Raquel G SoengasDepartment of Organic and Inorganic Chemistry, Instituto Universitario de Química Organometálica Enrique Moles, University of Oviedo Julián Clavería 8 33006 Oviedo Spain rsoengas@uniovi.es hrsolla@uniovi.es.ORCID https://orcid.org/0000-0001-8178-0034
Humberto Rodríguez-SollaDepartment of Organic and Inorganic Chemistry, Instituto Universitario de Química Organometálica Enrique Moles, University of Oviedo Julián Clavería 8 33006 Oviedo Spain rsoengas@uniovi.es hrsolla@uniovi.es.ORCID https://orcid.org/0000-0002-5394-5177

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Herein, a visible light-promoted metal-free protocol for the synthesis of nitrocyclopropanes under mild conditions is reported. Specifically, the process is driven by the photochemical activity of ternary EDA complexes formed upon complexation of α-bromonitrostyrenes and DIPEA in the presence of benzaldehyde. This reaction provides a variety of densely functionalized cyclopropanes with good selectivity under mild reaction conditions. Mechanistic investigations on the aspects of the process also demonstrate formation of the hypothesized EDA complex.

Identifiers

PMID40343315
PMCPMC12060227

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.