ArticleACS applied materials & interfaces2025
Transition-Metal Nitrides for High-Temperature Structural Colors.
Article in ACS applied materials & interfaces, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Transition-metal nitrides (TMNs), such as hafnium nitride (HfN), titanium nitride (TiN), and zirconium nitride (ZrN), have emerged as highly promising materials in photonics and plasmonics, drawing significant interest due to their optical properties comparable to those of conventional plasmonic materials like Ag and Ag, with remarkable thermal and chemical stability. While TMNs possess high bulk melting points and impressive resistance to degradation, the impact of scaling down to nanoscale dimensions and exposure to oxidizing environments under high temperatures on their optical properties remains largely underexplored. In this work, we establish a comprehensive experimental framework combining in situ optical characterization and ex situ surface analysis to explore the behavior of TMNs at 600 °C with exposure to oxygen. This oxidation process enables gradual color transitions in TMNs, thereby opening pathways for innovative applications in high-temperature structural color for printing. We further investigate aluminum oxide (Al
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